Co–N–GSgsrun.exe是什么程序么

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Single-atom dispersed Co–N–C catalyst: structure identification and performance for hydrogenative coupling of nitroarenes
Corresponding authors
State Key Laboratory of Catalysis, iChEM (Collaborative Innovation Center of Chemistry for Energy Materials), Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 ZhongShan Road, Dalian, China
University of Chinese Academy of Sciences, Beijing, China
National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei, China
Chem. Sci., 2016,7,
13 May 2016,
11 Jun 2016
First published online
13 Jun 2016
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Co–N–C catalysts are promising candidates for substituting platinum in electrocatalysis and organic transformations. The heterogeneity of the Co species resulting from high-temperature pyrolysis, however, encumbers the structural identification of active sites. Herein, we report a self-supporting Co–N–C catalyst wherein cobalt is dispersed exclusively as single atoms. By using sub-?ngstr?m-resolution HAADF-STEM in combination with XAFS and DFT calculation, the exact structure of the Co–N–C is identified to be CoN4C8-1-2O2, where the Co center atom is coordinated with four pyridinic N atoms in the graphitic layer, while two oxygen molecules are weakly adsorbed on Co atoms in perpendicular to the Co–N4 plane. This single-atom dispersed Co–N–C catalyst presents excellent performance for the chemoselective hydrogenation of nitroarenes to produce azo compounds under mild reaction conditions.
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